(1-Adamantyl)(2-methylphenyl)methanone
نویسندگان
چکیده
In the title compound, C(18)H(22)O, the dihedral angle between the carbonyl and benzene planes is 69.11 (6)°. In the adamantyl group, the three fused cyclo-hexane rings have almost ideal chair conformations, with C-C-C angles in the range 108.14 (11)-110.50 (11)°. No specific inter-molecular inter-actions (other than van der Waals inter-actions) are present in the crystal.
منابع مشابه
(1-Adamantyl)(3-aminophenyl)methanone
In the crystal sructure of the title compound, C(17)H(21)NO, the mol-ecular packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and additional weak N-H⋯π inter-actions, forming chains that propagate along the b axis. Conjugation of the carbonyl group and the benzene ring is rather attenuated due to a twisting of the carbonyl group from the plane of the benzene ring [torsion angle = 27...
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In the title compound, C(16)H(15)BrO(2), the dihedral angle between the benzene rings is 68.5 (2)°. In the crystal structure, mol-ecules are linked by weak C-H⋯O hydrogen bonds into chains parallel to the b axis.
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